Well I is an EE, at least that's what the piece of paper says. Using
'lower' battery is just fine but be aware that you are unbalancing the
charging system and the 'top' battery will get more charge than the lower.
A standard 'legal' CB shouldn't be much of a problem. Maybe just swap
batteries every few months or keep an eye on the acid level of the 'top'
battery.
As to a 24V to 12V converter, first of all we really need to concider that
it's actually 28V and 14V (respectively) with the engine running. Two
simple methods.
1) 20 ea silcon diodes of sufficient (and then some) rating to handle
current of device connected in series (forward biased) between 24V terminal
(plus of top battery) and the 12V lead of the radio.
2) 1ea 14V Zener diode (or suitable number of suitable voltage diodes to
make 14V) of proper current rating connected same as diode string in #1 above.
That is all.
je
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